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  2. Arylcyclohexylamine - Wikipedia

    en.wikipedia.org/wiki/Arylcyclohexylamine

    An arylcyclohexylamine is composed of a cyclohexylamine unit with an aryl moiety attachment. The aryl group is positioned geminal to the amine. In the simplest cases, the aryl moiety is typically a phenyl ring, sometimes with additional substitution. The amine is usually not primary; secondary amines such as methylamine or ethylamine, or ...

  3. Phencyclidine - Wikipedia

    en.wikipedia.org/wiki/Phencyclidine

    Phencyclidine or phenylcyclohexyl piperidine ( PCP ), also known in its use as a street drug as angel dust among other names, is a dissociative anesthetic mainly used recreationally for its significant mind-altering effects. [1] [5] PCP may cause hallucinations, distorted perceptions of sounds, and violent behavior.

  4. Cyclohexylamine - Wikipedia

    en.wikipedia.org/wiki/Cyclohexylamine

    Cyclohexylamine is used as an intermediate in synthesis of other organic compounds. It is the precursor to sulfenamide -based reagents used as accelerators for vulcanization. The amine itself is an effective corrosion inhibitor. It has been used as a flushing aid in the printing ink industry. [5]

  5. Eticyclidine - Wikipedia

    en.wikipedia.org/wiki/Eticyclidine

    Eticyclidine. Eticyclidine ( PCE, CI-400) is a dissociative anesthetic drug with hallucinogenic effects. It is similar in effects to phencyclidine but is slightly more potent. PCE was developed by Parke-Davis in the 1970s and evaluated for anesthetic potential under the code name CI-400, [2] but research into PCE was not continued after the ...

  6. Curtius rearrangement - Wikipedia

    en.wikipedia.org/wiki/Curtius_rearrangement

    Curtius rearrangement. The Curtius rearrangement (or Curtius reaction or Curtius degradation ), first defined by Theodor Curtius in 1885, is the thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. [1] [2] The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield ...

  7. Enantioselective synthesis - Wikipedia

    en.wikipedia.org/wiki/Enantioselective_synthesis

    Enantioselective synthesis, also called asymmetric synthesis, [1] is a form of chemical synthesis. It is defined by IUPAC as "a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric ( enantiomeric or diastereomeric) products in unequal ...

  8. Ring-opening metathesis polymerisation - Wikipedia

    en.wikipedia.org/wiki/Ring-opening_metathesis...

    Ring-opening metathesis polymerisation. In polymer chemistry, ring-opening metathesis polymerization ( ROMP) is a type of chain-growth polymerization involving olefin metathesis. The driving force of the reaction is relief of ring strain in cyclic olefins (e.g. norbornene or cyclopentene ). A variety of heterogeneous and homogeneous catalysts ...

  9. Ei mechanism - Wikipedia

    en.wikipedia.org/wiki/Ei_mechanism

    mechanism. In organic chemistry, the Ei mechanism ( Elimination Internal/Intramolecular ), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in ...