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A temperature coefficient describes the relative change of a physical property that is associated with a given change in temperature. For a property R that changes when the temperature changes by dT, the temperature coefficient α is defined by the following equation: Here α has the dimension of an inverse temperature and can be expressed e.g ...
The rate ratio at a temperature increase of 10 degrees (marked by points) is equal to the Q10 coefficient. The Q10 temperature coefficient is a measure of temperature sensitivity based on the chemical reactions. The Q10 is calculated as: where; T is the temperature in Celsius degrees or kelvin. Rewriting this equation, the assumption behind Q10 ...
Arrhenius equation. In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium ...
The rate of change of temperature with respect to pressure in a Joule–Thomson process (that is, at constant enthalpy ) is the Joule–Thomson (Kelvin) coefficient. This coefficient can be expressed in terms of the gas's specific volume V {\displaystyle V} , its heat capacity at constant pressure C p {\displaystyle C_{\mathrm {p} }} , and its ...
The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH⊖, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book ...
Viscosity depends strongly on temperature. In liquids it usually decreases with increasing temperature, whereas, in most gases, viscosity increases with increasing temperature. This article discusses several models of this dependence, ranging from rigorous first-principles calculations for monatomic gases, to empirical correlations for liquids.
Heat equation. Animated plot of the evolution of the temperature in a square metal plate as predicted by the heat equation. The height and redness indicate the temperature at each point. The initial state has a uniformly hot hoof-shaped region (red) surrounded by uniformly cold region (yellow). As time passes the heat diffuses into the cold region.
These first Heisler–Gröber charts were based upon the first term of the exact Fourier series solution for an infinite plane wall: (,) = = [ + ], [1]where T i is the initial uniform temperature of the slab, T ∞ is the constant environmental temperature imposed at the boundary, x is the location in the plane wall, λ is the root of λ * tan λ = Bi, and α is thermal diffusivity.