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The enthalpy of fusion is the amount of energy required to convert one mole of solid into liquid. For example, when melting 1 kg of ice (at 0 °C under a wide range of pressures ), 333.55 kJ of energy is absorbed with no temperature change. The heat of solidification (when a substance changes from liquid to solid) is equal and opposite.
Latent heat is energy released or absorbed by a body or a thermodynamic system during a constant-temperature process. Two common forms of latent heat are latent heat of fusion and latent heat of vaporization . These names describe the direction of energy flow when changing from one phase to the next: from solid to liquid, and liquid to gas.
Substituting into the Clapeyron equation =, we can obtain the Clausius–Clapeyron equation [7]: 509 = for low temperatures and pressures, [7]: 509 where is the specific latent heat of the substance. Instead of the specific, corresponding molar values (i.e. L {\displaystyle L} in kJ/mol and R = 8.31 J/(mol⋅K)) may also be used.
The specific enthalpy of fusion (more commonly known as latent heat) of water is 333.55 kJ/kg at 0 °C: the same amount of energy is required to melt ice as to warm ice from −160 °C up to its melting point or to heat the same amount of water by about 80 °C. Of common substances, only that of ammonia is higher.
Chvorinov's rule. Chvorinov's rule is a physical relationship that relates the solidification time for a simple casting to the volume and surface area of the casting. It was first expressed by Czech engineer Nicolas Chvorinov in 1940. [ 1][ 2]
The latent heat of fusion is about 264–289 kJ/kg. [14] Unlike some types of heat packs, such as those dependent upon irreversible chemical reactions, a sodium acetate heat pack can be easily reused by immersing the pack in boiling water for a few minutes, until the crystals are completely dissolved, and allowing the pack to slowly cool to ...
Paraffin candle. Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to melt above approximately 37 °C (99 °F), [ 2] and its boiling point is above 370 °C ...
In thermodynamics, the enthalpy of vaporization (symbol ∆Hvap ), also known as the ( latent) heat of vaporization or heat of evaporation, is the amount of energy ( enthalpy) that must be added to a liquid substance to transform a quantity of that substance into a gas. The enthalpy of vaporization is a function of the pressure and temperature ...