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In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat ( heat capacity) in a solid. [ 2] It treats the vibrations of the atomic lattice (heat) as phonons in a box in contrast to the Einstein photoelectron model, which treats the solid as many ...
Scale of temperature. Scale of temperature is a methodology of calibrating the physical quantity temperature in metrology. Empirical scales measure temperature in relation to convenient and stable parameters or reference points, such as the freezing and boiling point of water. Absolute temperature is based on thermodynamic principles: using the ...
Thus, they are essentially equations of state, and using the fundamental equations, experimental data can be used to determine sought-after quantities like G (Gibbs free energy) or H . [1] The relation is generally expressed as a microscopic change in internal energy in terms of microscopic changes in entropy , and volume for a closed system in ...
The third law of thermodynamics states that the entropy of a system at absolute zero is a well-defined constant. This is because a system at zero temperature exists in its ground state, so that its entropy is determined only by the degeneracy of the ground state. In 1912 Nernst stated the law thus: "It is impossible for any procedure to lead to ...
Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer
The Gibbs–Helmholtz equation is a thermodynamic equation used to calculate changes in the Gibbs free energy of a system as a function of temperature. It was originally presented in an 1882 paper entitled "Die Thermodynamik chemischer Vorgänge" by Hermann von Helmholtz. It describes how the Gibbs free energy, which was presented originally by ...
Thermal equation of state of solids. In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V. The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance ), while the thermal equation of state for ...
Newton's law of cooling. In the study of heat transfer, Newton's law of cooling is a physical law which states that the rate of heat loss of a body is directly proportional to the difference in the temperatures between the body and its environment. The law is frequently qualified to include the condition that the temperature difference is small ...