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The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called Gas Laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
The gas constant occurs in the ideal gas law: = = where P is the absolute pressure, V is the volume of gas, n is the amount of substance, m is the mass, and T is the thermodynamic temperature. R specific is the mass-specific gas constant. The gas constant is expressed in the same unit as molar heat.
Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant. Therefore, when the volume is halved, the pressure is doubled; and if the volume is doubled, the pressure is halved.
The empirical laws that led to the derivation of the ideal gas law were discovered with experiments that changed only 2 state variables of the gas and kept every other one constant. All the possible gas laws that could have been discovered with this kind of setup are:
Henry's law. In physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. It was formulated by the English chemist William Henry, who studied the topic in the early 19th ...
Charles' law (also known as the law of volumes) is an experimental gas law that describes how gases tend to expand when heated. A modern statement of Charles' law is: When the pressure on a sample of a dry gas is held constant, the Kelvin temperature and the volume will be in direct proportion. [ 1]
Avogadro's law states that "equal volumes of all gases, at the same temperature and pressure, have the same number of molecules ." [ 1] For a given mass of an ideal gas, the volume and amount (moles) of the gas are directly proportional if the temperature and pressure are constant. The law is named after Amedeo Avogadro who, in 1812, [ 2][ 3 ...
Kinetic theory of gases. The temperature of the ideal gas is proportional to the average kinetic energy of its particles. The size of helium atoms relative to their spacing is shown to scale under 1,950 atmospheres of pressure. The atoms have an average speed relative to their size slowed down here two trillion fold from that at room ...